Anion-Templated Assembly of a Supramolec
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James S. Fleming; Karen L. V. Mann; Charles-Antoine Carraz; Elefteria Psillakis;
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Article
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1998
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John Wiley and Sons
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English
⚖ 115 KB
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The templating effect of the tetrafluoroborate ion leads to assembly of four Co ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but