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Anion Control in the Self-Assembly of a Cage Coordination Complex

✍ Scribed by Ramón Vilar; D. Michael P. Mingos; Andrew J. P. White; David J. Williams


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
152 KB
Volume
37
Category
Article
ISSN
0044-8249

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Anion-Templated Assembly of a Supramolec
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The templating effect of the tetrafluoroborate ion leads to assembly of four Co ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but