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Chloride Anion Templated Synthesis and Crystal Structure of a Handcuff Catenane

✍ Scribed by Nicholas H. Evans; Dr. Christopher J. Serpell; Prof. Paul D. Beer


Book ID
102728708
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
528 KB
Volume
50
Category
Article
ISSN
0044-8249

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The synthesis of a topologically chiral in,out-bis-sulfonamide catenane and its "dimer" are reported. The structures of the amide wheel and of the catenane were resolved by X-ray analysis. NMR-titration of the monosulfonamide-wheel yielded conclusive association constants supporting the proposed reg