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Anion Templated Assembly of Mechanically Interlocked Structures

✍ Scribed by Matthew S. Vickers; Paul D. Beer

Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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The templating effect of the tetrafluoroborate ion leads to assembly of four Co ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but