The templating effect of the tetrafluoroborate ion leads to assembly of four Co ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but
✦ LIBER ✦
Anion-Templated Formation of Supramolecular Multinuclear Assemblies
✍ Scribed by Sander J. Wezenberg; Eduardo C. Escudero-Adán; Jordi Benet-Buchholz; Arjan W. Kleij
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 523 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0947-6539
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