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Anchimeric Assistance in Solvolysis of Haloalkylphosphines

✍ Scribed by Nouri Neamati-Mazraeh; Samuel P. McManus

Book ID
104233405
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
241 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis

Kinetic data are presented which reveal haloalkylphosphines undergo anchimerically-assisted cyclization with the ring-size preference 5 > 6 > 3 > 4. Also, phenylthio and diphenylphosphino groups are shown to have similar intramolecular nucleophilicities.

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