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Anchimeric assistance in vapor-phase acetate thermolysis

✍ Scribed by Daniel J. Kramer; Grant Gill Smith

Book ID
102444965
Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
310 KB
Volume
6
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The occurrence of anchimeric assistance in the vapor‐phase thermolysis of anti‐ and syn‐7‐acetoxy‐7‐methylnorbornene and 7‐acetoxy‐7‐methylnorborane has been investigated. The relative rates of thermolysis were found to be 1.9, 0.87, and 1.0, respectively. The nature of the transition state for ester thermolysis is discussed in light of the small amount of anchimeric assistance found in the thermolysis of the anti‐isomer.

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