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The anchimeric assistance in the ligand-coupling reactions of π-allylic palladium acetate complexes

✍ Scribed by Y. Takahashi; K. Tsukiyama; S. Sakai; Y. Ishii

Publisher: Elsevier Science
Year: 1970
Tongue: French
Weight: 213 KB
Volume: 11
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)98116-x

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✦ Synopsis

n-Allylic acetylacetonatopalladium complexes were found to react in the atmosphere of carbon monoxide to give allylic acetylacetones(1). This type of ligand coupling reactions could be applied generally for some allylic palladium complexes, in which a ligand other than halogen was included, that is acetate(Z), amines(2) and allylic groups(3).

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