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Catalyzed reactions of acetylene in vapor phase: Kinetics and mechanism of vapor phase synthesis of vinyl acetate over various metal acetate catalysts

โœ Scribed by I.B. Vasil'yeva; A.J. Gelbshtein; I.N. Tolsteekova; Dao Van T'yong


Book ID
113172575
Publisher
Elsevier Science
Year
1964
Tongue
English
Weight
178 KB
Volume
3
Category
Article
ISSN
0021-9517

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Supported palladium catalyzes the synthesis of vinyl acetate (VA) by oxyacetylation of ethylene. Alkali promoters increase activity and selectivity. The role of acetic acid ( \(\mathrm{HOAc}\) ) in these processes is not well understood. Activation energy studies show that HOAc alters the catalyst s