Anchimeric assistance in reactions of platinum(II) complexes
โ Scribed by Fred Basolo; Keith H. Stephen
- Book ID
- 107768339
- Publisher
- Elsevier Science
- Year
- 1966
- Weight
- 179 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0020-1650
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๐ SIMILAR VOLUMES
n-Allylic acetylacetonatopalladium complexes were found to react in the atmosphere of carbon monoxide to give allylic acetylacetones(1). This type of ligand coupling reactions could be applied generally for some allylic palladium complexes, in which a ligand other than halogen was included, that is
Kinetic data are presented which reveal haloalkylphosphines undergo anchimerically-assisted cyclization with the ring-size preference 5 > 6 > 3 > 4. Also, phenylthio and diphenylphosphino groups are shown to have similar intramolecular nucleophilicities.