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Concerted fragmentation and anchimerically assisted elimination in the solvolysis of 3-chloropropanthiols

✍ Scribed by C.A. Grob; B. Schmitz; A. Sutter; A.H. Weber


Book ID
104224501
Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
192 KB
Volume
16
Category
Article
ISSN
0040-4039

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✦ Synopsis


In contrast to 3-chloropropanols HO-i-i-t-Cl, the solvolytic reactions of


πŸ“œ SIMILAR VOLUMES


Competing Fragmentation, Substitution an
✍ Walter Fischer; Cyril A. Grob πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 German βš– 763 KB

## Abstract The unstrained 3‐chloroalcohols **1a**, **2a** and **3a** do not undergo solvolytic fragmentation in neutral and weakly acidic 80% ethanol, only substitution and elimination products being formed by the limiting __S__~__N__~__1__‐__E1__ mechanisms. This also applies to the corresponding