The 3-chloropropanols la, 2 and 2 undergo concerted olefin-forming fragmentation with sodium hydroxide in 80 vol., % ethanol. In addition, the acyclic compounds 2a and & undergo anchimerically assisted elimination. In the absence of -
β¦ LIBER β¦
Concerted fragmentation and anchimerically assisted elimination in the solvolysis of 3-chloropropanthiols
β Scribed by C.A. Grob; B. Schmitz; A. Sutter; A.H. Weber
- Book ID
- 104224501
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 192 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
In contrast to 3-chloropropanols HO-i-i-t-Cl, the solvolytic reactions of
π SIMILAR VOLUMES
Concerted fragmentation and anchimerical
β
W. Fischer; C.A. Grob
π
Article
π
1975
π
Elsevier Science
π
French
β 171 KB
Competing Fragmentation, Substitution an
β
Walter Fischer; Cyril A. Grob
π
Article
π
1978
π
John Wiley and Sons
π
German
β 763 KB
## Abstract The unstrained 3βchloroalcohols **1a**, **2a** and **3a** do not undergo solvolytic fragmentation in neutral and weakly acidic 80% ethanol, only substitution and elimination products being formed by the limiting __S__~__N__~__1__β__E1__ mechanisms. This also applies to the corresponding
Structures and energies of isomeric cycl
β
Schleyer, Paul v. R.; Bentley, T. William; Koch, Wolfram; Kos, Alexander J.; Sch
π
Article
π
1987
π
American Chemical Society
π
English
β 653 KB
The nature of the anchimeric assistance
β
Colin Eaborn; Paul D. Lickiss; Alan D. Taylor
π
Article
π
1988
π
Elsevier Science
π
English
β 225 KB
Anchimeric assistance by the Ξ³-N3 and Ξ³-
β
Colin Eaborn; M.Novella Romanelli
π
Article
π
1993
π
Elsevier Science
π
English
β 845 KB
Four-centered concerted ethane eliminati
β
Awadhesh Kumar; P.K. Chowdhury; K.V.S. Rama Rao; J.P. Mittal
π
Article
π
1992
π
Elsevier Science
π
English
β 634 KB