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Anchimeric assistance by the γ-N3 and γ-NCS groups in solvolysis of (Me3Si)2C(SiMe2 N3)(SiMe2Br) and (Me3Si)2C(SiMe2NCS)(SiMe2Br)

✍ Scribed by Colin Eaborn; M.Novella Romanelli

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
845 KB
Volume
451
Category
Article
ISSN
0022-328X

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The silanediols RN(SiMe3)Si(OSiMe3)(0H)2 (R = 2,4,6-were characterized by means of mass, IR and NMR (lH and Me3C6H2 4, 2,6-Me2C6H3 5 , and 2,6-iPr2C6H3 6) were prepa-2gSi) spectroscopy. Additionally, the molecular structures of red by the reactions of the respective silanetriols RN(SiMe3)-4 and 7 we