Multicomponent model of dimerizing charged hard spheres embedded in a rigid, uniform, and neutralizing background is proposed as a reference system to describe the equilibrium properties of liquid metals and alloys as well as metal-molten salt mixtures. The analytic solution of the associative mean
Analytic solution of the mean spherical approximation for ion-dipole model in a neutralizing background
β Scribed by M. F. Golovko; I. A. Protsykevich
- Publisher
- Springer
- Year
- 1989
- Tongue
- English
- Weight
- 886 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-4715
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π SIMILAR VOLUMES
General expressions for the Baxter factor correlation functions are obtained in the mean spherical approximation for a mixture of hard ions of arbitrary size and charge in a dipolar solvent. A method for the calculation of the total correlation functions for the model considered is proposed.
Tile mean spheriul approximation for a mi..ture of charged hard spheres in a uniform neutralizing background is solved anaIyticzlly\_ The factor correlation functions and the excess thermodynamic properties are explicitly expressed through a single parameter, which can be obtained by solving an alge
The mean spherical approximation for a multicomponent mixture of charged hard spheres with sticky interactions in a uniform neutralizing background is solved analytically. When the sticky parameters are of the form A v ~ w~wj +\_ vivj, then the correlation functions and the excess thermodynamic prop