✦ LIBER ✦

Mean spherical approximation for an arbitrary mixture of ions with surface adhesion in a neutralizing background

✍ Scribed by I.A. Protsykevich

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 320 KB
Volume: 232
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)01369-7

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✦ Synopsis

The mean spherical approximation for a multicomponent mixture of charged hard spheres with sticky interactions in a uniform neutralizing background is solved analytically. When the sticky parameters are of the form A v ~ w~wj +_ vivj, then the correlation functions and the excess thermodynamic properties are explicitly expressed through a single parameter F, which can be obtained by solving an algebraic equation. In the one-component case, an explicit expression for the parameter F is obtained.

📜 SIMILAR VOLUMES

General solution of the associative mean

General solution of the associative mean spherical approximation for the mixture of dimerizing ions in neutralizing background

✍ I.A. Protsykevich 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 335 KB

Multicomponent model of dimerizing charged hard spheres embedded in a rigid, uniform, and neutralizing background is proposed as a reference system to describe the equilibrium properties of liquid metals and alloys as well as metal-molten salt mixtures. The analytic solution of the associative mean