The mean spherical approximation for a multicomponent mixture of charged hard spheres with sticky interactions in a uniform neutralizing background is solved analytically. When the sticky parameters are of the form A v ~ w~wj +\_ vivj, then the correlation functions and the excess thermodynamic prop
General solution of the associative mean spherical approximation for the mixture of dimerizing ions in neutralizing background
β Scribed by I.A. Protsykevich
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 335 KB
- Volume
- 252
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Multicomponent model of dimerizing charged hard spheres embedded in a rigid, uniform, and neutralizing background is proposed as a reference system to describe the equilibrium properties of liquid metals and alloys as well as metal-molten salt mixtures. The analytic solution of the associative mean spherical approximation of the Wertheim's theory for associating fluids is obtained.
π SIMILAR VOLUMES
An analytical solution of Wertheim's associative Percus-Yevick ( APY) approximation for the n-component mixture of dimerizing hard spheres is presented. The solution is illustrated by the numerical results obtained for the two-component mixture with associative interaction only between particles of
An analytical solution of the two-density Ornstein-Zernike equation closed by the associative Percus-Yevick approximation for the multicomponent mixture of dimerizing adhesive hard spheres (DAHS) is obtained in closed form. This is the generalization of the previous solution for the one-component DA