✦ LIBER ✦

Solution of the associative Percus—Yevick approximation for the n-component mixture of dimerizing hard spheres

✍ Scribed by Yu.V. Kalyuzhnyi; I.A. Protsykevytch; M.F. Holovko

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 279 KB
Volume: 215
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)89253-e

No coin nor oath required. For personal study only.

✦ Synopsis

An analytical solution of Wertheim's associative Percus-Yevick ( APY) approximation for the n-component mixture of dimerizing hard spheres is presented. The solution is illustrated by the numerical results obtained for the two-component mixture with associative interaction only between particles of a different sort. In the limiting case of complete dimerization the results of the APY approximation are in good agreement with the predictions of the Monte Carlo simulation performed for the corresponding system of heteronuclear hard dumbbells. In this limit the present solution can be used as a simple analytical approach in the description of the system of heteronuclear hard dumbbells and their mixtures.

📜 SIMILAR VOLUMES

Solution of the associative Percus-Yevic

Solution of the associative Percus-Yevick approximation for the multicomponent mixture of dimerizing hard spheres with surface adhesion

✍ I.A. Protsykevich; Yu. Duda; M.F. Holovko 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 291 KB

An analytical solution of the two-density Ornstein-Zernike equation closed by the associative Percus-Yevick approximation for the multicomponent mixture of dimerizing adhesive hard spheres (DAHS) is obtained in closed form. This is the generalization of the previous solution for the one-component DA

Differential-difference equations for th

Differential-difference equations for the radial distribution function of hard rods and hard spheres under Percus-Yevick approximation

✍ M Chen 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 816 KB

General solution of the associative mean

General solution of the associative mean spherical approximation for the mixture of dimerizing ions in neutralizing background

✍ I.A. Protsykevich 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 335 KB

Multicomponent model of dimerizing charged hard spheres embedded in a rigid, uniform, and neutralizing background is proposed as a reference system to describe the equilibrium properties of liquid metals and alloys as well as metal-molten salt mixtures. The analytic solution of the associative mean

Solution of the compressibility equation

Solution of the compressibility equation of the adhesive hard-sphere model for mixtures

✍ B. Barboy 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 833 KB

Analytic solution of the mean spherical

Analytic solution of the mean spherical approximation for arbitrary mixture of hard ions and hard dipoles

✍ I.A. Protsykevich 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 302 KB

The influence of macromolecular crowding

The influence of macromolecular crowding on thermodynamic activity: Solubility and dimerization constants for spherical and dumbbell-shaped molecules in a hard-sphere mixture

✍ Otto G. Berg 📂 Article 📅 1990 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 973 KB

Macromolecules in solution can have large effects on the properties of other solutes through nonideal excluded-volume (crowding) interactions. Minton [ ( 1983 ) Mol. Cell. Biochem. 55, 119-1401 has calculated such effects by treating the macromolecules as a hard-sphere fluid in a background of an in