Explicit solution of the mean spherical model for ions and dipoles
✍ Scribed by W. Pérez-Hernández; L. Blum
- Publisher
- Springer
- Year
- 1981
- Tongue
- English
- Weight
- 142 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0022-4715
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A solution to the mean spherical model for a mkture of chxged hard spheres of equal concentration and opposite ch;lrge, and hard dipoles, all of equal size, is given. The excess thermodynamic properties and the structure of the system depend on only 3 pxameters, which are the solution of a set of 3
General expressions for the Baxter factor correlation functions are obtained in the mean spherical approximation for a mixture of hard ions of arbitrary size and charge in a dipolar solvent. A method for the calculation of the total correlation functions for the model considered is proposed.