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Mean spherical model for hard ions and dipoles: Thermodynamics and correlation functions

✍ Scribed by Fernando Vericat; Lesser Blum


Publisher
Springer
Year
1980
Tongue
English
Weight
450 KB
Volume
22
Category
Article
ISSN
0022-4715

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πŸ“œ SIMILAR VOLUMES


Mean spherical model for a mixture of ch
✍ L. Blum πŸ“‚ Article πŸ“… 1974 πŸ› Elsevier Science 🌐 English βš– 228 KB

A solution to the mean spherical model for a mkture of chxged hard spheres of equal concentration and opposite ch;lrge, and hard dipoles, all of equal size, is given. The excess thermodynamic properties and the structure of the system depend on only 3 pxameters, which are the solution of a set of 3

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General expressions for the Baxter factor correlation functions are obtained in the mean spherical approximation for a mixture of hard ions of arbitrary size and charge in a dipolar solvent. A method for the calculation of the total correlation functions for the model considered is proposed.

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✍ M.F. Holovko; V.I. Kapko πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 764 KB

A simple electrolyte in a polar solvent is modelled by a mixture of polar hard spheres and charged hard spheres of different sizes. The model includes ion-ion, ion-dipole and dipole-dipole associations. The analytical solution of the associative mean spherical approximation (AMSA) for this model is