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Analysis of the reaction and quenching channels in a H + O 2 ( a 1 Δ g ) system

✍ Scribed by Sharipov, A S; Starik, A M


Book ID
121491085
Publisher
Royal Swedish Academy of Sciences
Year
2013
Tongue
English
Weight
384 KB
Volume
88
Category
Article
ISSN
0031-8949

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O2∗ (a 1Δg) in the reaction of H+O3
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✍ Diane V. Michelangeli; Kuang-Yul Choo; Ming-Taun Leu 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 998 KB

The generation of metastable O, ('Xg+) and Oz('Ag) in the H + 0, system of reactions was studied by the flow discharge chemiluminescence detection method. In addition to the Oz('Pg') and Oz(' , H0,(2A~oo) + H02(2AlohO), H02(zA~o,) + HO,(zA~oo), and H Oz(2A~oo) --+ H0,(2A&,o) emissions were detected

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The same chemiluminescent spectrum of HNO was obtained in both the reaction systems of 0(3P) + CaHe + NO + 02 (\* A,)/02 and H + NO + 02( 'Ag)/Oa. The reaction mechanism for producing the excited HNO is proposed to be -HNO('A') + 02 ( 'Ag) + HNO(3A", + 0s (3X,) , HNOc3A") + 02 ('A,) --t HNO('A") +