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Quenching of by O( 3P ), O 2 ( a 1 Δ g ), and other gases

✍ Scribed by Kenner, Rex D.; Ogryzlo, Elmer A.


Book ID
120063387
Publisher
NRC Research Press
Year
1983
Tongue
French
Weight
424 KB
Volume
61
Category
Article
ISSN
0008-4042

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Quenching of O2(1Δg) by organic molecule
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Rate constants for the quenching of Oz(lAg) by 2,3dimethyl-2-butene and triethylamine have been determined in a discharge-flow system when NO2 is added to eliminate atomic oxygen from the system. The results indicate that in many previous determinations of rate constants for the quenching of 02(lAg)

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The quenching rate constants of 02('Ag) with n-butylamine, diethylamine, dipropylamine, dibutylamine, and tripropylamine have been determined in a discharge flow system. The rate constants are found to be (1.6 i . 0.2) x lo3, (8.5 2 0.6) X lo4, (9.8 ? 0.5) x lo4, (2.1 2 0.1) x lo5, and (8.6 2 0.5) x

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molecules from a discharge have been analyzed by the emission of the infrared atmospheric (0.0) bancfat 12700 A and by the emission of the atmospheric (0,O) band at 7619 A due to the energy pooling reaction ## 202(1Agj -+02('Cs) + 02(%;) . Particular rate constants for the deactivation of 02(1 A