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An unusual example of a rapid spin-equilibrium iron complex

✍ Scribed by Yonezo Maeda; Naoto Tsutsumi; Yoshima Takashima

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
359 KB
Volume
88
Category
Article
ISSN
0009-2614

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✦ Synopsis

Rccciwd 5 Jan~nry 1982, III final form I6 rcbrunry 1982 Bls(N-( I-benzoyl-7--propyl~dcnc)-2-pyr~dylmclhyl~m~n~to)uon(lll) hc\alluorophosphatc (Tc(bzpa)~Pr~) IS shown to be 3 spin-cqmhbrlum compound bclwccn low-(S= 112) and high-(S = S/2) spin slates dcpcnding on tcmpcrature, and to have lllc unusu.d property that the relawhon lime of lhc spm change is shorter than the Xlossbwcr hfctlme (I x lo-7 s) or iron_ 57 (I = 3/Z) m the solid SIP~C.

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