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Complexation of 2,6-Bis(3-pyrazolyl)pyridine–Bis(thiocyanato)iron(II) with a Bridging 4,4′-Bipyridine: A New Example of a Dinuclear Spin Crossover Complex

✍ Scribed by Dalila Fedaoui; Yacine Bouhadja; Abdellah Kaiba; Philippe Guionneau; Jean-François Létard; Patrick Rosa

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 236 KB
Volume: 2008
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200700708

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✦ Synopsis

Abstract

Investigation of the coordination behavior of 2,6‐bis(3‐pyrazolyl)pyridine–bis(thiocyanato)iron(II) towards bridging ligands led to the discovery of a novel dinuclear complex showing spin‐crossover. Chemical and structural characterization and a first report of physical properties are presented.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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