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Synthesis, structure and magnetic property of a new mixed-valence copper(I/II) complex derived from 3,5-bis(pyridin-2-yl)-1,2,4-triazole

✍ Scribed by Jing-Cai Chen; Ai-Ju Zhou; Sheng Hu; Ming-Liang Tong; Ye-Xiang Tong

Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
310 KB
Volume
794
Category
Article
ISSN
0022-2860

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## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4‐isobutyl‐3,5‐di(2‐pyridyl)‐4__H__‐1,2,4‐triazole (ibdpt) with M(ClO~4~)~2~Β·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~