## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4‐isobutyl‐3,5‐di(2‐pyridyl)‐4__H__‐1,2,4‐triazole (ibdpt) with M(ClO~4~)~2~·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~
✦ LIBER ✦
New Reactivity of 4-Amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole: Synthesis and Structure of a Mononuclear Species, a Dinuclear Species, and a Novel Tetranuclear Nickel(II) Rectangle Box, and Magnetic Properties of the Dinuclear and Tetranuclear Complexes
✍ Scribed by Ming-Liang Tong; Chao-Gang Hong; Ling-Ling Zheng; Meng-Xia Peng; A. Gaita-Arińo; Juan Modesto Clemente Juan
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 240 KB
- Volume
- 2007
- Category
- Article
- ISSN
- 1434-1948
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## Abstract As a probe of the dinucleating ability of the known but little studied bis‐bidentate ligand 3,5‐di(2‐pyridyl)‐4‐(1__H__‐pyrrol‐1‐yl)‐4__H__‐1,2,4‐triazole (pldpt) its reactivity towards MX~2~·6H~2~O (M = Co^II^, Ni^II^ and Zn^II^; X = ClO~4~^–^ and BF~4~^–^) as well as Cu(ClO~4~)~2~·6H~