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The First Example of an Equilibrium between a Carbene and an Isomeric Carbyne Transition Metal Complex

✍ Scribed by Pablo González-Herrero; Birgit Weberndörfer; Kerstin Ilg; Justin Wolf; Helmut Werner

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 173 KB
Volume: 39
Category: Article
ISSN: 0044-8249
DOI: 10.1002/1521-3773(20000915)39:18<3266::aid-anie3266>3.0.co;2-#

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✦ Synopsis

Dedicated to Professor Herbert W. Roesky on the occasion of his 65th birthday

By attempting to generate a cationic, possibly solvated, vinylideneruthenium(ii) complex with a 14-electron configuration at the metal center, we recently found that the reaction of the starting material 1 with HBF 4 in dichloromethane/ diethyl ether leads to the formation of the ruthenium carbyne 3 instead of the anticipated ruthenium vinylidene 2 [Eq. ( 1)]. [1] Although compound 3 is a highly efficient catalyst

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