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Further example of unusually large quadrupole splitting in high-spin iron(II) complexes

✍ Scribed by Sulekh Chandra; K.B. Pandeya; G.L. Sawhney; J.S. Baijal


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
188 KB
Volume
61
Category
Article
ISSN
0009-2614

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An extremely large 57Fe Mössbauer quadru
✍ David J. Evans 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 158 KB

The zero-field, solid state, 57Fe M~3ssbauer spectrum of the trinuclear high-spin iron(II) complex [Fe3(SC6H2~Pr3 -2,4,6)4{N(SiMe3)2} 2 ] has been recorded at 77 K. 'Unusually' large quadrupole splitting values (> 3.5 mm s -~) are observed for both the distorted trigonal planar (3.60 mm s-J) and dis