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An improvement to the synthesis of deuterated meso-tetraphenylporphyrins

✍ Scribed by Motoko S. Asano; Hiroshi Abe; Youkoh Kaizu

Book ID: 102367881
Publisher: John Wiley and Sons
Year: 2006
Tongue: French
Weight: 146 KB
Volume: 49
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.1077

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✦ Synopsis

An improved method for the synthesis of deuterated tetraphenylporphyrins (TPPs) is reported. In this method, deuterium labelling at the pyrrole-b-position is increased to more than 95 at%. TPP is the most widely used synthetic porphyrin and high deuterium incorporation is essential for spectroscopic studies and kinetic studies involving relaxation processes.

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