An improved method for the synthesis of deuterated tetraphenylporphyrins (TPPs) is reported. In this method, deuterium labelling at the pyrrole-b-position is increased to more than 95 at%. TPP is the most widely used synthetic porphyrin and high deuterium incorporation is essential for spectroscopic
✦ LIBER ✦
An efficient approach to the synthesis of tetrahydroquinazoline and cyclooctapyrimidine derivatives of meso-tetraphenylporphyrins
✍ Scribed by João P.C. Tomé; Augusto C. Tomé; Maria G.P.M.S. Neves; JoséA.S. Cavaleiro
- Book ID
- 104256828
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 211 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Novel tetrahydroquinazoline and cyclooctapyrimidine derivatives of TPP were obtained by thermal extrusion of SO2 from a porphyrin-pyrimidine fused 3-sulfolene in the presence of N-(4-nitrophenyl)maleimide.
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