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The synthesis of isomeric dithymidyl-phosphorus(V)-meso-tetraphenylporphyrins

✍ Scribed by Gerard Kian-Meng Goh; Leszek Czuchajowski

Book ID
101289075
Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
58 KB
Volume
01
Category
Article
ISSN
1088-4246

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✦ Synopsis

The synthesis of three novel axial dinucleosides was successfully accomplished. The compounds are 5' -O, 5' -O -dithymidyl -phosphorus(V) -meso -tetraphenylporphyrin, 5' -O, 3' -O -dithymidyl -phosphorus(V) -meso -tetraphenylporphyrin, and 3' -O, 3' -O -dithymidyl -phosphorus-(V)-tetraphenylporophyrin. These compounds could provide a lead toward the synthesis of an oligo-porphyrinyl DNA analogue that represents a system containing phosphorus(V) porphine units axially connected through the 5'-O-thymidine-3'-O bridges.

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