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An experimental and analytical study of acetylene and ethylene oxidation behind shock waves

✍ Scribed by Casimir J. Jachimowski

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
715 KB
Volume
29
Category
Article
ISSN
0010-2180

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✦ Synopsis

An experimental and analytical study of the oxidation of acetylene and ethylene behind incident shock waves was carried out over the temperature range 1815-2365 K at reaction pressures between 1.1 and 1.7 atm. The oxidation process was monitored by measuring radiation from carbon dioxide, carbon monoxide, and the reaction O + CO ~ CO 2 + hr. The recordcd emission profiles were analyzed to obtain concentrations for carbon dioxide, carbon monoxide, and the product of oxygen atom and the carbon monoxide concentrations. On the basis of this data and induction time data reported in the literature, kinetic models for acetylene and ethylene oxidation were assembled. The effect of adding other reactions to the proposed mechanisms is also discussed.

EXPERIMENTAL APPARATUS AND MEASUREMENTS

All the experiments were carried out behind incident shock waves in an 8.9-cm i.d. stainless-steel shock tube. Two different test sections were used during these studies. The experiments with ethyl-

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