Gas-Phase Reactions of Nitronium Ions with Acetylene and Ethylene: An Experimental and Theoretical Study
β Scribed by Fernando Bernardi; Fulvio Cacace; Giulia de Petris; Federico Pepi; Ivan Rossi; Anna Troiani
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 195 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0947-6539
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Gas-phase nucleophilic substitution reactions of Y-benzyl chlorides with X-phenoxide and Xthiophenoxide nucleophiles were investigated theoretically using the PM3 semi-empirical MO method. The Leffler-Grunwald rate-equilibrium and BrΓΈnsted correlations predict that the degree of bond formation in th
3c) together with BF3 or SbF5. Conductivity measurements in CH3N02 confirm that (4a) and (4b) are 1 : 1 electrolytes. (30-c), R=CnH,, X=H, C1, F; (3d), R = H , X = F (4a, b), R = CbHS, anion = BF: or S b E (4c).