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An expansion of the Hamiltonian for the vibrating-rotating molecule in terms of the S-vector formalism

✍ Scribed by Anna Mae Walsh Bakke

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
486 KB
Volume
40
Category
Article
ISSN
0022-2852

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📜 SIMILAR VOLUMES

Vibration—rotation Hamiltonian of tetrah
Vibration—rotation Hamiltonian of tetrahedral molecules in the local-mode model
✍ Mark S. Child; Qingshi Zhu 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 231 KB

The stretching vibration-rotation Hamiltonian of tetrahedral molecules is derived in the local-mode model. The result shows that the effective rotational Hamiltonian of a local-mode state gives rise to symmetric-top rotational energy levels, which are quantitatively in good agreement with experiment