𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Explicit introduction of the Born-Oppenheimer κ in expansions of the vibration-rotation Hamiltonian

✍ Scribed by Thorvald Pedersen


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
111 KB
Volume
80
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Calculation of Rotation–Vibration Energy
✍ V. špirko; Markus Mengel; Per Jensen 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 330 KB

has been used to determine effective bending potentials and reduced masses for C 3 in the lowest stretching vibrational states by performing a Born-Oppenheimer separation of the bending and stretching motions. These calculations were based on a potential energy function obtained in a least-squares f

Vibration—rotation Hamiltonian of tetrah
✍ Mark S. Child; Qingshi Zhu 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 231 KB

The stretching vibration-rotation Hamiltonian of tetrahedral molecules is derived in the local-mode model. The result shows that the effective rotational Hamiltonian of a local-mode state gives rise to symmetric-top rotational energy levels, which are quantitatively in good agreement with experiment