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Vibration—rotation Hamiltonian of tetrahedral molecules in the local-mode model

✍ Scribed by Mark S. Child; Qingshi Zhu

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
231 KB
Volume
184
Category
Article
ISSN
0009-2614

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✦ Synopsis

The stretching vibration-rotation Hamiltonian of tetrahedral molecules is derived in the local-mode model. The result shows that the effective rotational Hamiltonian of a local-mode state gives rise to symmetric-top rotational energy levels, which are quantitatively in good agreement with experiments.

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