Vibration-rotation Hamiltonian of the bent XYZ molecule
β Scribed by Miu Yung Chan; Paul M. Parker
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 667 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-2852
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π SIMILAR VOLUMES
The stretching vibration-rotation Hamiltonian of tetrahedral molecules is derived in the local-mode model. The result shows that the effective rotational Hamiltonian of a local-mode state gives rise to symmetric-top rotational energy levels, which are quantitatively in good agreement with experiment
A method for using a single Kindependent grid for problems where otherwise a basis of associated Legendre functions or the corresponding K-dependent grids would be employed, specific&y for calculating the rotational-vibrational energy Ievels of a triatomic molecule, has been described and tested. K