2004 Other bioactive products ## Other bioactive products U 1300 An Efficient Asymmetric Synthesis of Tarchonanthuslactone. -Key steps of the new asymmetric synthesis of tarchonanthuslactone (X) are the enzymatic transformation of diketo ester (I) to lactone (II) in excellent stereoselectivity,
An Efficient Asymmetric Synthesis of Tarchonanthuslactone
β Scribed by Dieter Enders; Daniel Steinbusch
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 111 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-193X
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An asymmetric total synthesis of Prostaglandin E 1 (5) has with the Corey CBS catalyst gave the Ο-side chain 7 with ΟΎ96% ee. Conjugate addition using the reaction with been achieved in a two-component coupling process. The chiral hydroxycyclopentenone 6 was readily available from dilithiocyanocuprat