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An Efficient Asymmetric Synthesis of Tarchonanthuslactone.

✍ Scribed by Dieter Enders; Daniel Steinbusch

Publisher: John Wiley and Sons
Year: 2004
Weight: 155 KB
Volume: 35
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200411210

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✦ Synopsis

2004

Other bioactive products

Other bioactive products U 1300

An Efficient Asymmetric Synthesis of Tarchonanthuslactone.

-Key steps of the new asymmetric synthesis of tarchonanthuslactone (X) are the enzymatic transformation of diketo ester (I) to lactone (II) in excellent stereoselectivity, and the construction of the tarchonanthuslactone skeleton (IX) by an umpolung technique. -(ENDERS*,

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