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An apparent isotope anomaly in the reaction CH3 + H/D

✍ Scribed by Mark Brouard; Michael J. Pilling


Book ID
103025004
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
634 KB
Volume
129
Category
Article
ISSN
0009-2614

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## Abstract The kinetic isotope effects in the reaction of methane (CH~4~) with Cl atoms are studied in a relative rate experiment at 298 Β± 2 K and 1013 Β± 10 mbar. The reaction rates of ^13^CH~4~, ^12^CH~3~D, ^12^CH~2~D~2~, ^12^CHD~3~, and ^12^CD~4~ with Cl radicals are measured relative to ^12^CH~