The effect on the thermal rate constant and the differential cross-sections of varying the dimensionality of quantum scattering calculations of a polyatomic reaction is investigated. The rotating bond approximation (RBA, 3D) and a rotating line approximation (RLA, 2D) are used for the CH, + OH + CH,
β¦ LIBER β¦
An apparent isotope anomaly in the reaction CH3 + H/D
β Scribed by Mark Brouard; Michael J. Pilling
- Book ID
- 103025004
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 634 KB
- Volume
- 129
- Category
- Article
- ISSN
- 0009-2614
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## Abstract The kinetic isotope effects in the reaction of methane (CH~4~) with Cl atoms are studied in a relative rate experiment at 298 Β± 2 K and 1013 Β± 10 mbar. The reaction rates of ^13^CH~4~, ^12^CH~3~D, ^12^CH~2~D~2~, ^12^CHD~3~, and ^12^CD~4~ with Cl radicals are measured relative to ^12^CH~