Direct ab initio dynamic calculations are performed on the reactions of atomic hydrogen with GeD(n)(CH(3))(4-n) (n = 1-4) over the temperature range 200-2000 K at the PMP4SDTQ/6-311 +G(3df,2p)//MP2/6-31 +G(d) (for n = 2-4) and G2//MP2/6-31 +G(d) (for n = 1) levels. The corresponding k(H)/k(D) ratios
Isotope effects in the elimination of H and D atoms by dissociative charge transfer reactions of H+2 and CH+4 ions with isotopic methanes
β Scribed by P. Ardelean; V. Mercea
- Publisher
- Elsevier Science
- Year
- 1975
- Weight
- 276 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0020-7381
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