𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A high pressure rate constant for CH3 + H and an analysis of the kinetics of the CH3 + H → CH4 reaction

✍ Scribed by Roger Patrick; Michael J. Pilling; Graham J. Rogers


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
927 KB
Volume
53
Category
Article
ISSN
0301-0104

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Rate constants for H + CH4, CH3 + H2, an
✍ J. W. Sutherland; M.-C. Su; J. V. Michael 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 230 KB

## Abstract The Laser Photolysis‐Shock Tube technique coupled with H‐atom atomic resonance absorption spectrometry has been used to study the reaction, H + CH~4~ → CH~3~ + H~2~, over the temperature range, 928–1697 K. Shock‐tube studies on the reverse of this reaction, CH~3~ + H~2~ → H + CH~4~, usi

Sensitivity of the H + CH3 → CH4 recombi
✍ Ronald J. Duchovic; William L. Hase 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 325 KB

Using a potential-energy surface obtained in part from ab initio calculations, the H + CH3 -CH4 bimolecular rate constant at T = 300 K is determined from a Monte Carlo classical trajectory study. Representing the C-H stretching potential with n standard Morse fun&on instead ofthe ab inirio curveincr

C2D5I dissociation and D+CH3 → CH2D+H at
✍ M.-C. Su; J.V. Michael 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 129 KB

The shock tube technique with H-and D-atom atomic resonance absorption spectrometry detection has been used to study the thermal decomposition of C 2 D 5 I and the reaction, 3 2 over the temperature ranges 924-1370 and 1294-1753 K, respectively. First-order rate constants for the thermal decomposit

Kinetics and mechanism of the reaction H
✍ G. K. Moortgat; F. ŠSlemr; P. Warneck 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 845 KB

The reaction of hydrogen atoms with methyl nitrite was studied in a fast-flow system The associated biusing photoionization mass spectrometry and excess atomic hydrogen. molecular rate coefficient can be expressed by k, = (4.3 f 0.9) x 10-13 exp [ -(1900 f 110) cal/mol . R T ] cm3/molecule . sec in

Unimolecular reactions of the isolated i
✍ Richard D. Bowen; Alex. W. Colburn; Peter J. Derrick 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 858 KB

The reactions of ten metastable immonium ions of general structure R'R2C=NH+C4H9 (R' = H, R2 = CH, , C2H, ; R' = R2 = CH,) are reported and discussed. Elimination of C4H, is usually the dominant fragmentation pathway. This process gives rise to a Gaussian metastable peak; it is interpreted in terms