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An acyl-Claisen approach to the synthesis of lignans and substituted pyrroles

✍ Scribed by Barker, David (author);Dickson, Benjamin (author);Dittrich, Nora (author);Rye, Claire E. (author)

Book ID
120254734
Publisher
International Union of Pure and Applied Chemistry
Year
2012
Tongue
English
Weight
658 KB
Volume
84
Category
Article
ISSN
0033-4545

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An acyl-Claisen approach to the synthesi
An acyl-Claisen approach to the synthesis of lignans and substituted pyrroles
✍ Barker, David (author);Dickson, Benjamin (author);Dittrich, Nora (author);Rye, C πŸ“‚ Article πŸ“… 2012 πŸ› International Union of Pure and Applied Chemistry 🌐 English βš– 658 KB

The acyl-Claisen rearrangement, also called a zwitterionic aza-Claisen rearrangement, allows for the synthesis of 2,3-__syn__-substituted morpholine pent-4-eneamides with high levels of diastereoselectivity. A wide variety of alkyl and aryl substituents can be introduced with yields highly dependent