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A new approach for the synthesis of fused pyrroles. The synthesis of acyl substituted pyrrolo[1,2-x]azines

✍ Scribed by Anton Čopar; Branko Stanovnik; Miha Tišler

Book ID
112130809
Publisher
Journal of Heterocyclic Chemistry
Year
1993
Tongue
English
Weight
218 KB
Volume
30
Category
Article
ISSN
0022-152X

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The acyl-Claisen rearrangement, also called a zwitterionic aza-Claisen rearrangement, allows for the synthesis of 2,3-__syn__-substituted morpholine pent-4-eneamides with high levels of diastereoselectivity. A wide variety of alkyl and aryl substituents can be introduced with yields highly dependent