The acyl-Claisen rearrangement, also called a zwitterionic aza-Claisen rearrangement, allows for the synthesis of 2,3-__syn__-substituted morpholine pent-4-eneamides with high levels of diastereoselectivity. A wide variety of alkyl and aryl substituents can be introduced with yields highly dependent
✦ LIBER ✦
An Ireland−Claisen Approach to Lignans: Synthesis of the Putative Structure of 5- epi -Eupomatilone-6
✍ Scribed by Hutchison, John M.; Hong, Sang-phyo; McIntosh, Matthias C.
- Book ID
- 127015399
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 168 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0022-3263
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An Alternative Diastereospecific Approach to (±)-Samin and 2,6-Diaryl-3,7-dioxabicyclo[3.3.0]octane [Furanofuran] Lignans Based on the Ireland-Claisen Rearrangement of Unsaturated Oxa-macrolides. -Ireland-Claisen rearrangement of the macrolide (II) gives stereospecifically the tetrahydrofurancarbox