An approach to the tremulane skeleton: Synthesis of (±)-6a-epi-tremulenolide B and related hydroazulenes
✍ Scribed by Werner Tochtermann; Torsten Panitzsch; Thorsten Habeck; Christian Wolff; Eva-Maria Peters; Karl Peters; Hans Georg von Schnering
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 868 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0040-4020
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
The construction of the 5-7-6 tricyclic skeleton of guanacastepene A, including the quaternary carbons, has been achieved. The C-11 and C-8 quaternary carbons were constructed by cuprate addition and carbene insertion, respectively. The 5-7-6 tricyclic core was generated by a selective aldol and SmI