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Aminophosphonite-phosphite and aminophosphonite-phosphinite ligands with mixed chirality: preparation and catalytic applications in asymmetric hydrogenation and hydroformylation

✍ Scribed by E Cesarotti; S Araneo; I Rimoldi; S Tassi

Book ID: 104422493
Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 133 KB
Volume: 204-205
Category: Article
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(03)00301-7

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## Abstract A new chiral aminophosphine ligand 6,6′‐dimethoxy‐2,2′‐bis(diphenylphosphinoamino) biphenyl (DMBDPPABP) was prepared and its rhodium complex was found to be an effective catalyst for the asymmetric hydrogenation of amidoacrylic add and its derivatives. The effects of solvent and reactio