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Use of heterogeneous asymmetric hydrogenation for the preparation of a chiral phosphinite and its application as a ligand in homogeneous asymmetric hydrogenation

โœ Scribed by Bakos, Jozsef; Toth, Imre; Marko, Laszlo


Book ID
118024349
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
297 KB
Volume
46
Category
Article
ISSN
0022-3263

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A new chiral dipyridylphosphine ligand X
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A new chiral dipyridylphosphine ligand Xyl-P-Phos has been synthesized and the structure of (S)-Xyl-P-Phos oxide has been characterized by single crystal X-ray diffraction. The ruthenium complex of this ligand, Ru(R-Xyl-P-Phos)(C 6 H 6 )Cl 2 , has been found to be a highly active, enantioselective a