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Synthesis of a new chiral bisphosphine ligand, MOCBP, and its use in rhodium(I)-catalyzed asymmetric hydrogenation of a cyclic enamide

✍ Scribed by Toshiaki Morimoto; Noriya Nakajima; Kazuo Achiwa


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
237 KB
Volume
6
Category
Article
ISSN
0957-4166

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A new chiral dipyridylphosphine ligand Xyl-P-Phos has been synthesized and the structure of (S)-Xyl-P-Phos oxide has been characterized by single crystal X-ray diffraction. The ruthenium complex of this ligand, Ru(R-Xyl-P-Phos)(C 6 H 6 )Cl 2 , has been found to be a highly active, enantioselective a