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Novel Chiral Aminophosphine Ligand: Synthesis and Application in Asymmetric Catalytic Hydrogenation Reaction

✍ Scribed by Chen Yi-Xin; Li Yue-Ming; Lam Kim-Hung; Chan Albert Sun-Chi

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 421 KB
Volume: 21
Category: Article
ISSN: 0256-7660
DOI: 10.1002/cjoc.20030210116

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✦ Synopsis

Abstract

A new chiral aminophosphine ligand 6,6′‐dimethoxy‐2,2′‐bis(diphenylphosphinoamino) biphenyl (DMBDPPABP) was prepared and its rhodium complex was found to be an effective catalyst for the asymmetric hydrogenation of amidoacrylic add and its derivatives. The effects of solvent and reaction temperature on enantioselectivity were also studied.

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