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Synthesis of Novel BINOL-Derived Chiral Bisphosphorus Ligands and Their Application in Catalytic Asymmetric Hydrogenation.

✍ Scribed by Yong-Gui Zhou; Xumu Zhang


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
33
Category
Article
ISSN
0931-7597

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Novel Chiral Aminophosphine Ligand: Synt
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## Abstract A new chiral aminophosphine ligand 6,6′‐dimethoxy‐2,2′‐bis(diphenylphosphinoamino) biphenyl (DMBDPPABP) was prepared and its rhodium complex was found to be an effective catalyst for the asymmetric hydrogenation of amidoacrylic add and its derivatives. The effects of solvent and reactio