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Aminolysis of esters. I. Kinetics and mechanism in anhydrous doxane

✍ Scribed by Shawali, A. Sami A. S.; Biechler, Sydney S.; Biechler, Sydney S.

Book ID
121211602
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
733 KB
Volume
89
Category
Article
ISSN
0002-7863

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Kinetics and mechanism of aminolysis of
Kinetics and mechanism of aminolysis of aliphatic esters in aprotic solvents
✍ Agu-TΓ΅nis Talvik; Ants Tuulmets; Evi Vaino πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 52 KB πŸ‘ 2 views

Kinetic studies were carried out on the aminolysis reactions of substituted aliphatic esters in a variety of aprotic solvents. The reaction rate is strongly affected by inductive and steric effects of substituents in the acyl group, rising more than 10 4 -fold from cyanoacetate to trifluoroacetate.