Amide Functional Initiators for Transition-Metal-Mediated Living Radical Polymerization
β Scribed by Limer, Adam; Haddleton, David M.
- Book ID
- 118242488
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 93 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
A series of initiators have been developed for living radical polymerization of methyl methacrylate (MMA) mediated by ruthenium(If) complexes [e.g., RuCI2(PPh3)3; Ph = C6H5]. These initiators include chloromethanes, ~-chloroesters, ct-chloroketones, and cc-bromoesters, among which CCI3COCH3, CHCI2CO
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## Abstract βTemplate initiatorβ' platforms (**1**) have been designed for expressing the sequence information in a template in radical polymerization. Thus, we demonstrated the structural adequacy of **1** consisting of two initiating sites placed __ortho__ to each other in benzene: one for living